Show this safety data sheet to the doctor in attendance. Acute exposure guideline levels aegls for piperidine cas. Page 1 of 9 msds dimethylformamide material safety data sheet msds dimethylformamide 1. When heated to decomposition, it emits highly toxic fumes of nitrogen oxides. The cas register number of piperidine,4,4dimethyl is 4045301. Material is hygroscopic, and readily absorbs water from air. Piperidine is a cyclic secondary amine, which can be considered as. The piperidine hydrochloride, with the cas registry number 6091447, is also known as piperidine, hydrochloride 1. Piperidine can be prepared either by nickel catalyzed hydrogenation of pyridine or by cobalt catalyzed hydrogenolysis of tetrahydrofurylamine 53 it forms adducts with.
Dangerous, when exposed to heat, flame, or oxidizers. Additionally, phone and email consultation services are available to provide counseling on test submission, result. Hexahydropyridine recommended use laboratory chemicals. Piperidine dea list i chemical, reagent is an organic compound in the form of a colorless fuming liqid with a ammonia like smell. Oqema has established itself at the forefront of the global chemical industry. Learn to walk like a penguin to prevent winter falls.
The name comes from the genus name piper, which is the latin word for pepper. Piperidine, reagentplus, 99% c5h11n hexahydropyridine. The guiding principles of oqema have always been to establish long term relationships with customers and suppliers alike to build sustainable and profitable business for all parties. Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone. Used as chemical reagent in the synthesis of organic compounds, it is also used as a solvent and as a bas. Extinguish with alcoholresistant foam, carbon dioxide, dry powder or water fog. Articles of piperidine hydrochloride are included as well. Piperidine,3,5dimethyl cas 35794117 msds guidechem. Ethyl nbocpiperidine4carboxylate cas 142851034 msds. Piperidine is a cyclic secondary amine, which can be considered as a parent molecular structure for many alkaloids. Product and company identification space synonyms softwood plywood oriented strand board osb hardboard standard, tempered, perforated, paneling lumber products engineered lumber lvl, woodijoists. Keeping the center of gravity over your front foot. Identification of the substancemixture and of the companyundertaking 1. Safety data sheet sds osha hazcom standard 29 cfr 1910.
Identification of the substancemixture and of the companyundertaking product name. The source is also providing more information like the publication year, authors and more. Certificate of analysis coa specification sheet pdf. Lachrymator substance which increases the flow of tears. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Material safety data sheet biphenyl central campus. Piperidine evolves explosive concentrations of vapor at normal room temperatures. Safety data sheet a university in missouri, college in. I have found out that somehow it reacts with the api in the headspace vial i see piperidine perfectly as a standard solution of 67 ppm but not when spiking the api. It belongs to the product categories of piperidine. Student disability services cornell health, level 5 110 ho plaza ithaca, ny 148533102 phone. If inhaled if breathed in, move person into fresh air.
Piperidine acute exposure guideline levels for selected. Experimental studies, case reports, and anecdotal data. These sdss are designed to provide essential information. This heterocyclic amine consists of a sixmembered ring containing five methylene units and one nitrogen. In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes.
When released into the air, this material is expected to have a halflife between 1 and 10 days. In case of contact, immediately flush skin with plenty of water. Sigmaaldrich offers sigmaaldrich104094, piperidine for your research needs. It has a role as a reagent, a protic solvent, a base, a catalyst, a plant metabolite, a. Piperidine is a colorless liquid with a bp of 106c and an unpleasant odor. Extend your arms to keep your balance, point your feet slightly outward, keeping your knees loose and. Safety data sheet creation date 29jun2010 revision date 14feb2020 revision number 4 1. Materials safety data sheets benzaldehyde 4 this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. The molecular formula about this chemical is c 7 h 15 n and the molecular weight is 1.
Its reagent grade means its purity is suitable for use in analytical testing labs and chemical reactions. July 2007 page 5 of 10 liquid density at boiling point and 1 atm. Always check your browsers address bar before you enter your netid password to make sure the address starts with cornell. Piperidine 4carbaldehyde c6h11no cid 14495648 structure, chemical names, physical and chemical properties, classification, patents, literature, biological. Download for offline reading, highlight, bookmark or take notes while you read piperidine.
Material safety data sheet according to eec directives 91155eec and 93112ec dplubricant blue 20000201 product name. It also can be called as 4,4dimethylpiperidine hydrochloride and the systematic name about this chemical is 4,4dimethylpiperidine. Page 112 safety data sheet sds osha hazcom standard 29 cfr 1910. Piperidine is an azacycloalkane that is cyclohexane in which one of the carbons is replaced by a nitrogen. Sds of 4amino1bocpiperidine, safety data sheets, cas. I am trying to analyze piperidine as a residual solvent in an api by gchs. Piperidine analytical standard hexahydropyridine sigma. Piperidine alkaloids have been identified as containing a saturated piperidine ring, and are mostly derived from lysine. The information above is believed to be accurate and represents the best information currently available to us. Hazards identification emergency overview appearance.
Chemical storage and segregation cornell university. Under the authority of the federal advisory committee act faca p. Piperidine safety data sheet according to the federal. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Piperidine1carboxamidinium ethyl carbonate article pdf available in acta crystallographica section e structure reports online 68pt 12. Piperidine is a reactive compound and forms complexes with the salts of heavy.
Uses advised against food, drug, pesticide or biocidal product use. Piperazine material safety data sheet us version date prepared. This heterocyclic amine consists of a sixmembered ring containing five methylene bridges ch 2 and one amine bridge nh. Structure, preparation, reactivity, and synthetic applications of.
Piperidine is an organic compound with the molecular formula ch 2 5 nh. The alkaloids are widespread among the apiaceae, solanaceae. Find msds or sds, a coa, data sheets and more information. Avoid 1perchlorylpiperidine and oxidizing materials. With a focus on providing the highest level of service. When released into the air, this material is expected to be readily degraded by reaction with photo chemically produced hydroxyl radicals.
When released into the air, this material is expected to hav e. Academic student disability services cornell university. Material safety data sheet material name wood and wood products. Piperidine is corrosive to skin and eyes on contact. The occupational safety and health administrations osha hazard communication standard 29 cfr 1910. Piperidine hydrochloride cas 6091447 msds guidechem.
Piperidine based drug discovery outlines the complexities of piperidine scaffold use in drug discovery, including derivative chemistry, structural properties, methods of synthesis and practical implementations. Material safety data sheet benzaldehyde pure section 1 chemical section 1 chemical product and company identification msds name. Find product specific information including uses, structure,cas, msds, protocols and references. Bazarova and migoukina 1975 reported an irritation threshold for piperidine of 90 mgm 3 26 ppm in human volunteers. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Material safety data sheet pyridine msds section 1.
It is a colorless liquid with an odor described as objectionable, and typical of amines. Piperidine is present in black pepper piper nigrum. Piperidine is listed as a table ii precursor under the united nations convention against illicit traffic in narcotic drugs and psychotropic substances due to its use peaking in the 1970s in the clandestine manufacture of pcp 11phenylcyclohexyl piperidine, also known as angel dust, sherms, wet, etc. Hexahydropyridine hydrochloride catalog of chemical suppliers, buyers, custom synthesis companies and equipment manufacturers piperidine, hydrochloride 6091447 chemical identification rtecs number. Material safety data sheet west liberty university.
The mature black pepper fruit contains a specific substance piperine. Ethyl 1tertbutyloxycarbonylisonipecotate, ethyl 1tertbutoxycarbonyl4piperidinecarboxylate, piperidine 1,4dicarboxylic acid 1tertbutyl ester 4ethyl ester empirical formula hill notation. Piperidine dea list i chemical, reagent 110894 p1146. Piperidine is as polar as diethyl ether or benzene, but is less polar compared to chloroform or ethyl acetate. Piperidine hexahydropyridine c5h11n 85,15 gmol concentration casno. Piperidine msds material safety data sheet or sds, coa and coq, dossiers, brochures and. National institute for occupational safety and health. Cuweblogin is a component of cornell universitys central authentication service. Used as chemical reagent in the synthesis of organic compounds, it is also used as a solvent and as a base. Take the time to validate and double check the source of. Piperidine scaffolds are the cornerstones of over 70 commercialized drugs including multiple blockbusters. Structure, preparation, reactivity, and synthetic applications of piperidine and its derivatives ebook written by m. Nformylpiperidine is a polar aprotic solvent with better hydrocarbon solubility than other amide solvents, and 2,2,6,6tetramethylpiperidine is highly sterically hindered base, useful because of its low nucleophilicity and high solubility in organic solvents. Page 112 safety data sheet sds msds authoring services.
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